During this thesis, the point of interest is at the examine of recent catalytic houses of unsupported nanoporous metals in heterogeneous natural reactions lower than liquid-phase stipulations. the writer used to be the 1st to manufacture nanoporous copper with tunable nanoporosity and practice it for natural reactions. The catalyst will be reused as much as ten occasions with no lack of catalytic job. additionally, the writer constructed the hugely selective semihydrogenation of alkynes utilizing nanoporous gold as a catalyst for the 1st time, affording Z-alkenes in a hundred% selectivity, which can't be learned by way of conventional catalysts. all the effects defined the following might help readers to improve new catalytic functionality of nanoporous metals for natural reactions.
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